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Ok this one caught my interest, so I actually thought about it.  I came up with a few songs, but nothing that really resonated.  Then, while I was waiting for iTunes to load so I could browes my playlists for insperation, I suddenly remembered driving in the car with my best friend and popping in the tape of the group she had introduced me to a few weeks earlier.  This song was the first one she played for me and I loved it instantly.  So my highschool theme song is "Prince of Darkness" by the Indigo Girls.